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138

2016

أوابك العلمية لعام

ص لبحوث العلمية الفائزة بجائزة

عدد خا

مجلة النفط والتعاون العربي

161

العدد

- 2017

أربعون

المجلد الثالث و ال

Re-refining of Used Lubricating Oil and its Economic and Environmental Implications

15

Detergents: Detergents are alkaline in nature and react with acids which form during

the combustion of fuel.

Anti-wear agents: They keep soot and combustion products in suspension thereby

preventing their precipitation as sludge.

Corrosion inhibitors: They protect metal surface from corrosion

Viscosity improvers: They are additives that increase the viscosity of the fluid

throughout its useful temperature range.

Antifoam additives: these substances prevent foaming which can occur as a result of air

entrapment in lube oil.

Pour point depressants: they are used to prevent rapid increase in the viscosity which

can occur due to crystallization, at low temperatures, of the paraffinic waxes present in

lube oil.

3.2.2 Contaminants of used lubricating oil

As pointed out earlier, lubricating oils lose their initial properties as a result of

accumulation of contaminants and chemical changes experienced during their use. The

presence of degraded additives and by-products of degradation render used lubricating

oils more toxic and harmful to health and environment than virgin base oils

(Motshumiet et al, 2013). The main types of contaminants of potential concern are

caused due to the following reasons (UNEP, 2012):

- Normal engine wear produces metallic particles w

- hich contaminate the lubricating oil.

- Water resulting from the combustion of fuel in the engine may pass into the

lubricating oil and can ultimately lead to sludge formation.

- Incomplete fuel combustion in the engine may result in the contamination of the

lube oil

- As a result of the combustion process, carcinogenic substances such as Polycyclic

Aromatic Hydrocarbons (PAH), are formed.

- Soot and carbon may form as a result of incomplete combustion, especially during

warm-up with a rich mixture.

- Unburnt gasoline or diesel can pass into the lubricant.

- Metals (Iron, Copper, and Aluminium) which are released due to normal engine

wear, road dust, can find their way into the lubricating oil.